Thermal stability increases down the group because the size of the cation (positive ion) increases, so the lattice energy of the carbonate decreases, but the lattice energy of the oxide decreases faster. Carbonates of metal: Thermal stabilityThe carbonates of alkali metals except lithium carbonate are stable to heat. It describes and explains how the thermal stability of the compounds changes as you go down the Group. But, experimentally, order is reverse. The higher the temperature needed to decompose something, the more thermally stable it is. Solution for group 1 elements with that of group 2 on the basis of the following:… The Facts. The effect of heat on the Group 2 carbonates. 2. Hence, Thermal stability order : $\ce{MgCO3 CaCO3 SrCO3 BaCO3}$ Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? I cannot wrap my head around this. By contrast, the least soluble Group 1 carbonate is lithium carbonate. From Li to Cs, due to larger ion size, hydration enthalpy decreases. The term "thermal decomposition" describes splitting up a compound by heating it. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. All these carbonates decompose on heating to give CO 2 and metal oxide. Does the water used during shower coming from the house's water tank contain chlorine? The quote from your text: So the stability that you are referring to is thermal stability.This is an important detail. Going down group II, the ionic radii of cations increases. The term "thermal decomposition" describes splitting up a compound by heating it. You may need to download version 2.0 now from the Chrome Web Store. From Li to Cs, thermal stability of carbonates increases. 6. 1. Zinc carbonate and sodium hydroxide? Carbonate Structure. • Generally increases down the group. Down the group, the carbonates require more heating to decompose. Get answers by asking now. The larger compounds further down require more heat than the lighter compounds in order to decompose. The decomposition temperatures again increase down the Group. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. • 18. In group 1 and 2, the nitrates and carbonates get more stable down the group. rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. This decreases the charge density and the ability of the cation to polarize the anion. So thermal stability increases. The carbonates For example, Group 2 carbonates are virtually insoluble in water. Upon heating, carbonates decompose into oxide and carbon dioxide; The thermal stability of group-1 and group-2 carbonates increase down the group. (substitute Na, K … This means that the enthalpy change from the carbonate to the oxide becomes more negative so more heat is needed to decompose it. The rest of the Group 1 carbonates do not decompose at laboratory temperatures, although at higher temperatures this becomes possible. If "X" represents any one of the elements: It's how resistant a molecule is to decomposition at higher temperatures. Your IP: 185.35.187.96 A simple relationship between the reactivity of the metal and the stability of its compounds, such as the carbonate here, will have to suffice. What is the  molar concentration of sodium nitrate .? For example, alkali metal salts such as sulptlates, carbonates, nitrates and perchlorates possess greater stability than the corresponding salts of less reactive metals, or the corresponding free acids. THE thermal stabilities of salts containing the same anion are well known to differ for different cations. It means the stability increases from M g C O 3 to B a C O 3 . If "X" represents any one of the elements: Another way to prevent getting this page in the future is to use Privacy Pass. All the Group 2 carbonates and their resulting oxides exist as white solids. The rest of group 1 follow the same pattern. The carbonates become more thermally stable down the group. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Explanation: New questions in Chemistry. All the alkaline earth metals form carbonates (MCO 3). All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. because down the group polarizing power of cation decreases. The carbonates of alkaline earth metals also decompose on heating to form oxide and carbon dioxide. I am a metal and placed above iron in the activity series. So what is thermal stability? However, carbonate of lithium, when heated, decomposes to form lithium oxide. How many grams of glucose would be formed in a reaction in which 23.576 grams of carbon dioxide were consumed? Favourite answer Thermal stability increases down the group because the size of the cation (positive ion) increases, so the lattice energy of the carbonate … Thermal stability of Alkaline earth metals carbonates increases down the group. When metal carbonates are heated, they break down to … Thermal Stability is the decomposition of a compound on heating. The electron cloud of anion is distorted to a lesser extent. Add your answer and earn points. The effect of heat on the Group 2 carbonates. Thermal stability The carbonates of alkali metals are stable towards heat. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. At an elementary level, the relative thermal stability of the carbonates of the metals cannot easily be explained in terms of simple ideas of bonding in these compounds. Cloudflare Ray ID: 61032405aebff166 Group 2 Oxides & Hydroxides w/ Water & Dilute Acid (6:58) Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) Completing the CAPTCHA proves you are a human and gives you temporary access to the web property. The same occurs in group 1. If you are on a personal connection, like at home, you can run an anti-virus scan on your device to make sure it is not infected with malware. I know stability increases as you go down group 2, please explain why in language a good A level student can understand. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. * Due to same reason, carbonates of group-1 are more stable than those of group-2. Stability of metal carbonates One common reaction of any metal carbonates is known as thermal decomposition. spontaneous combustion - how does it work? All of these carbonates are white solids, and the oxides that are produced are also white solids. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. 3H2O, evaluated by in situ laboratory parallel-beam X-ray powder diffraction: New constraints on CO2 sequestration within minerals, Journal of Hazardous Materials 178, no.1-3 1-3 (Jun 2010): 522–528. It consists of a carbon atom surrounded by three oxygen atom in a trigonal planar arrangement. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Join Yahoo Answers and get 100 points today. In group1,it is found that the thermal stability of hydroxides,carbonates,nitrates sulphates etc. The higher the temperature required to decompose something, the more thermally stable it will be. What or who protects you from residue and odour? Please enable Cookies and reload the page. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Explanation: In all cases, for a particular set of e.g. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. You will often find unusual properties for the first member of a group. To test what you've learned from this lesson- Answer to question 23 the calcium ion has a larger charge (2+) thatn the potassium ion (1+). If ice is less dense than liquid water, shouldn’t it behave as a gas? Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. (i) All the alkaline earth metals form carbonates (MCO 3). Thermal decomposition is the term given to splitting up a compound by heating it. So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . Which of the following is likely to occur after decreasing the pressure of a liquid. If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. Thermal decomposition is the term given to splitting up a compound by heating it. As we go down the group, the carbonates have to be heated more strongly before they will decompose. Thermal Stability. Magnesium carbonate (the most soluble one I have data for) is soluble to the extent of about 0.02 g per 100 g of water at room temperature. Performance & security by Cloudflare, Please complete the security check to access. All these carbonates decompose on heating to give CO 2 and metal oxide. The thermal stability of the hydrogen carbonates Thermal Stability is the decomposition of a compound on heating. All of these carbonates are white solids, and the oxides that are produced are also white solids. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. Nature of carbonates and bicarbonates: Alkali metal carbonates and bicarbonate stability increases down the group. Decomposition becomes more difficult and thermal stability increases. 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